The caption read: José Theodore with Vincent Damphousse and René-Charles, Céline Dion/René Angélil’s son.
This was at a golf tournament at Club de Golf le Mirage on Monday, July 22, 2013. It seems this Club is owned by Celine Dion and Rene Angelil and they have this event every year, and José usually attends.
So thanks to Joey for catching that for us. I think it's kind of fun how Rene-Charles has very famous parents and is used to celebrities being around, but he still wants his picture taken with the hockey players. :)